Hi,
How to design policies depends heaviliy on your use case.
Let us make an example by taking natural language as a metapher:
The XACML specification defines the grammar of the policy language and define how to interprete/evaluate it. The vocabulary has to be defined by the writer.
So in my opinion I don't think that you will find a simple "how to write a policy" tutorial that will help you.
I think it will be the easiest way to read through the XACML specification (e.g.
http://docs.oasis-open.org/xacml/2.0/access_control-xacml-2.0-core-spec-os.pdf). Especially the non-normative parts (Chapter 1-4) explain XACML very well.
You could also look through example policies you'll find on the internet.
Then I would suggest you to use an XML-Editor that supports schema validation for writing policies by yourself.
Florian has written a thesis that deals about an approach on "how could policies being analysed/developed" (see
http://www.herasaf.org/uploads/theses/2008/2008_fall_MasterStudentResearchProject_Analysis_of_Access_Control_Policies.pdf).
He made also a case study in that thesis. Maybe that could help you.
Regards,
René